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101.
102.
103.
Jae-Seok Kim Anna Liza Bais Sun-hee Kang Jaehoon Lee Kihong Park 《Journal of Atmospheric Chemistry》2011,68(3):251-263
Ammonia has a short residence time in the atmosphere and rapidly neutralizes acid gases that occur near its source, requiring a rapid measurement system for ammonia and particulate ammonium concentrations to better understand their sources, temporal variation of ammonia emissions, and the formation of secondary ammonium aerosols. A semi-continuous measurement system, consisting of a diffusion scrubber, a particle growth chamber, an air-liquid separator, and a fluorescent detector, was developed to determine both gaseous ammonia (NH3) and particulate ammonium (NH 4 + ) in PM2.5 in the ambient atmosphere of Gwangju, South Korea, during the months of March, April, July, and September of 2007. During the sampling periods, the average concentrations of ammonia and ammonium were found to be 2.33?±?1.29 μg/m3 and 1.89?±?0.99 μg/m3, respectively. Although the average gaseous ammonia concentration was highest in March, the particulate ammonium concentration was higher during the warmer season, reaching 2.08?±?1.07 μg/m3 and 2.32?±?0.94 μg/m3 in April and July, respectively, while only 1.68?±?0.61 μg/m3 in March and 1.24?±?0.99 μg/m3 in September. It is proposed that the higher availability of acid species during the warmer months produced a significant amount of particulate ammonium sulfate. Diurnal fluctuation of ammonia and ammonium during the warmer months showed that their peak time occurred at approximately 10:00 am. Both ammonia and ammonium concentrations were better correlated during the warmer months than during the cooler months. Further, the data suggest that the ammonia and ammonium were measured under well dispersed conditions, and multiple sources contributed to the ammonia at the sampling site. 相似文献
104.
To better constrain sampling strategies for observing biologically sensitive parameters in ground water, we vigorously pumped for 120 h a lightly pumped well completed in a confined glacial aquifer while observing how various physical and chemical parameters evolve in the water produced. The parameters commonly monitored when sampling a well stabilized within about an hour, after 5 wellbore volumes were produced; these parameters include temperature, pH, dissolved oxygen, oxidation-reduction potential (Eh), and electrical conductivity. The concentrations of ferrous iron, sulfide, and sulfate and various biological or biologically sensitive parameters, including the concentrations of dissolved hydrogen and methane, direct cell counts, and the microbial community profile, in contrast, required more than 8 h or 36 well volumes to stabilize. We interpret this result to mean that the zone of influence of the wellbore on biologic processes in the aquifer extends beyond the commonly recognized zone where physical properties are affected. A second period of adjustment of these biologically sensitive parameters began after about 50 h of pumping, following displacement of 230 wellbore volumes, and continued to the end of the experiment. During this period, the cell density and the composition of the microbial community suspended in the water samples changed. This finding indicates that the microbial community in and near the wellbore changed in response to pumping and the changes affected aspects of the composition of water produced from the well. The study demonstrates the importance of allowing adequate pumping time when sampling ground water for the analysis of biologically sensitive parameters. 相似文献
105.
On the relative importance of the driving forces of plate motion 总被引:4,自引:0,他引:4
106.
107.
Jong-Chan Park Woohan Kim Tae Woong Chung Chang-Eob Baag Jin-Han Ree 《Geophysical Journal International》2007,169(3):1103-1114
We evaluate the stress field in and around the southern Korean Peninsula with focal mechanism solutions, using the data collected from 71 earthquakes ( ML = 1.9–5.2) between 1999 and 2004. For this, the hypocentres were relocated and well-constrained fault plane solutions were obtained from the data set of 1270 clear P -wave polarities and 46 SH / P amplitude ratios. The focal mechanism solutions indicate that the prevailing faulting types in South Korea are strike-slip-dominant-oblique-slip faultings with minor reverse-slip component. The maximum principal stresses (σ1 ) estimated from fault-slip inversion analysis of the focal mechanism solutions show a similar orientation with E–W trend (269°–275°) and low-angle plunge (10°–25°) for all tectonic provinces in South Korea, consistent with the E–W trending maximum horizontal stress (σHmax ) of the Amurian microplate reported from in situ stress measurements and earthquake focal mechanisms. The directions of the intermediate (σ2 ) and minimum (σ3 ) principal stresses of the Gyeongsang Basin are, however, about 90 deg off from those of the other tectonic provinces on a common σ2 –σ3 plane, suggesting a permutation of σ2 and σ3 . Our results incorporated with those from the kinematic studies of the Quaternary faults imply that NNW- to NE-striking faults (dextral strike-slip or oblique-slip with a reverse-slip component) are highly likely to generate earthquakes in South Korea. 相似文献
108.
Jin-Yong Lee Jeong-Yong Cheon Hyung-Pyo Kwon Hee-Sung Yoon Seong-Sun Lee Jong-Ho Kim Joung-Ku Park Chang-Gyun Kim 《Environmental Geology》2006,51(4):581-593
Attenuation characteristics of landfill leachate were examined for two uncontrolled landfills in Korea. The two landfills containing municipal wastes without appropriate bottom liner and leachate treatment system have different landfill age, waste volume, and most importantly different hydrogeologic settings. One landfill (Cheonan landfill) is situated in an open flat area while the other (Wonju landfill) is located in a valley. Variations of various parameters including dissolved organic carbon (DOC), dissolved oxygen (DO), alkalinity, pH, electrical conductivity (EC), redox potential (ORP), ammonia (NH3), nitrate (NO3−), sulfate (SO42−), and chloride (Cl−) were examined along groundwater flow path. All these parameters were analyzed every month for a year. In the interior of the landfills, typical anaerobic conditions revealed by low DO and NO3 concentrations, negative ORP values, high NH3, alkalinity, and Cl− concentrations were observed. Generally, higher levels of contaminants (DOC, NH3, and Cl−) were detected in the dry season while they were greatly lowered in the wet season. Significantly, large decrease of Cl- concentration in the wet season indicates that the dilution or mixing is one of dominant attenuation mechanisms of leachate. But detailed variation behaviors in the two landfills are different and they were largely dependent on permeability of surface and subsurface layers. The intermediately permeable surface of the landfills receives part of direct rainfall infiltration but most rainwater is lost to fast runoff. The practically impermeable surface of clayey silt (paddy field) at immediately adjacent to the Cheonan landfill boundary prevented direct rainwater infiltration and hence redox condition of the ground waters were largely affected by that of the upper landfill and the less permeable materials beneath the paddy fields prohibited dispersion of the landfill leachate into down gradient area. In the Wonju landfill, there are three different permeability divisions, the landfill region, the sandy open field and the paddy field. Roles of the landfill and paddy regions are very similar to those at the Cheonan. The very permeable sandy field receiving a large amount of rainwater infiltration plays a key role in controlling redox condition of the down gradient area and contaminant migration. This paper reports details of the attenuation and redox conditions of the landfill leachates at the two uncontrolled landfills. 相似文献
109.
Evolution of the eastern margin of Korea: Constraints on the opening of the East Sea (Japan Sea) 总被引:2,自引:2,他引:2
Han-Joon Kim Gwang Hoon Lee Hyeong-Tae Jou Hyun-Moo Cho Hai-Soo Yoo Gun-Tae Park Ji-Soo Kim 《Tectonophysics》2007,436(1-4):37-55
We interpreted marine seismic profiles in conjunction with swath bathymetric and magnetic data to investigate rifting to breakup processes at the eastern Korean margin that led to the separation of the southwestern Japan Arc. The eastern Korean margin is rimmed by fundamental elements of rift architecture comprising a seaward succession of a rift basin and an uplifted rift flank passing into the slope, typical of a passive continental margin. In the northern part, rifting occurred in the Korea Plateau that is a continental fragment extended and partially segmented from the Korean Peninsula. Two distinguished rift basins (Onnuri and Bandal Basins) in the Korea Plateau are bounded by major synthetic and smaller antithetic faults, creating wide and considerably symmetric profiles. The large-offset border fault zones of these basins have convex dip slopes and demonstrate a zig-zag arrangement along strike. In contrast, the southern margin is engraved along its length with a single narrow rift basin (Hupo Basin) that is an elongated asymmetric half-graben. Analysis of rift fault patterns suggests that rifting at the Korean margin was primarily controlled by normal faulting resulting from extension rather than strike-slip deformation. Two extension directions for rifting are recognized: the Onnuri and Hupo Basins were rifted in the east-west direction; the Bandal Basin in the east–west and northwest–southeast directions, suggesting two rift stages. We interpret that the east–west direction represents initial rifting at the inner margin; while the Japan Basin widened, rifting propagated southeastward repeatedly from the Japan Basin toward the Korean margin but could not penetrate the strong continental lithosphere of the Korean Shield and changed the direction to the south, resulting in east–west extension to create the rift basins at the Korean margin. The northwest–southeast direction probably represents the direction of rifting orthogonal to the inferred line of breakup along the base of the slope of the Korea Plateau; after breakup the southwestern Japan Arc separated in the southeast direction, indicating a response to tensional tectonics associated with the subduction of the Pacific Plate in the northwest direction. No significant volcanism was involved in initial rifting. In contrast, the inception of sea floor spreading documents a pronounced volcanic phase which appears to reflect asthenospheric upwelling as well as rift-induced convection particularly in the narrow southern margin. We suggest that structural and igneous evolution of the Korean margin, although it is in a back-arc setting, can be explained by the processes occurring at the passive continental margin with magmatism influenced by asthenospheric upwelling. 相似文献
110.
Study on the kinetics of iron oxide leaching by oxalic acid 总被引:2,自引:0,他引:2
Suong Oh Lee Tam Tran Yi Yong Park Seong Jun Kim Myong Jun Kim 《International Journal of Mineral Processing》2006,80(2-4):144-152
The presence of iron oxides in clay or silica raw materials is detrimental to the manufacturing of high quality ceramics. Although iron has been traditionally removed by physical mineral processing, acid washing has been tested as it is more effective, especially for extremely low iron (of less than 0.1% w/w). However, inorganic acids such as sulphuric or hydrochloric acids easily contaminate the clay products with SO42− and Cl−, and therefore should be avoided as much as possible. On the other hand, if oxalic acid is used, any acid left behind will be destroyed during the firing of the ceramic products. The characteristics of dissolution of iron oxides were therefore investigated in this study.The dissolution of iron oxides in oxalic acid was found to be very slow at temperatures within the range 25–60 °C, but its rate increases rapidly above 90 °C. The dissolution rate also increases with increasing oxalate concentration at the constant pH values set within the optimum range of pH2.5–3.0. At this optimum pH, the dissolution of fine pure hematite (Fe2O3) (105–140 μm) follows a diffusion-controlled shrinking core model. The rate expression expressed as 1 − (2 / 3)x − (1 − x)2 / 3 where x is a fraction of iron dissolution was found to be proportional to [oxalate]1.5.The addition of magnetite to the leach liquor at 10% w/w hematite was found to enhance the dissolution rate dramatically. Such addition of magnetite allows coarser hematite in the range 0.5–1.4 mm to be leached at a reasonable rate. 相似文献